The following list details all key members of staff at Kepier.
| Senior Leadership Team: | ||
| Mrs N. Ashton | – | Principal |
| Mr D. Kilkenny | – | Assistant Principal |
| Mr C. Langley | – | Assistant Principal |
| Mr A. Warkman | – | Assistant Principal |
| Mr C. Devlin | – | Assistant Principal |
| Miss A. Allen | – | Associate Senior Leader |
| Mr S. Forsyth | – | Associate Senior Leader |
| Mrs D. Minns | – | Director of Finance and Resources |
| Mrs L. Cossey | – | Lead Practitioner |
| Miss D. Ross | – | Lead Practitioner |
| Mrs D. Thorley | – | Lead Practitioner |
| Mr S. Van-Lindon | – | Senior Leader – Pastoral |
| Mrs J. Stephenson | – | Senior Leader – Science |
| Mr S. Anderson | – | Senior Leader – Maths |
| Mr P. Farley | – | Senior Leader – English |
| Mrs S. Read | – | Senior Leader – Inclusion |
| Mrs P. Watson | – | SENDCo |
| Year Managers: | ||
| Mrs D. Crompton | – | Year 7 |
| Mr P. Tait | – | Year 8 |
| Mrs D. Adamson | – | Year 9 |
| Mrs C. Brown | – | Year 10 |
| Mrs A. Parker | – | Year 11 |
| Curriculum Leaders: | ||
| Mr L. Lightfoot | – | Art & Design |
| Mrs S. Read | – | SEMH |
| Mr P. Farley | – | English |
| Mr S. Anderson | – | Mathematics |
| Mrs J. Stephenson | – | Science |
| Mrs G. Bolt | – | Business |
| Miss A. Allen | – | Geography/Culture and Wellbeing |
| Mrs L. Mirley | – | Health and Social Care |
| Mr S. Forsyth | – | History |
| Mr T. Mayer | – | Information Technology |
| Mr M. Forster | – | Media Studies |
| Mrs S. Stewart-Grey | – | Modern Foreign Languages |
| Mr C. Smith | – | Music |
| Mr N. Osmond | – | Physical Education |
| Mrs A. Andrews | – | Technology |
